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id="tmyrlzez" class="n_con" id="c_detail_wrap"> <p> 電解除磷設(shè)備的反應(yīng)原理是以鋁、鐵等金屬為陽極，在直流電的作用下，陽極被溶蝕，產(chǎn)生Al、Fe等離子，在經(jīng)一系列水解、聚合及亞鐵的氧化過程，發(fā)展成為各種羥基絡(luò)合物、多核羥基絡(luò)合物以至氫氧化物，使廢水中的膠態(tài)雜質(zhì)、懸浮雜質(zhì)凝聚沉淀而分離，同時(shí)帶電的污染物顆粒在電場(chǎng)中泳動(dòng)，其部分電荷被電極中和而促使其脫穩(wěn)聚沉。廢水進(jìn)行電解絮凝處理時(shí)，不僅對(duì)膠態(tài)雜質(zhì)及懸浮雜質(zhì)有凝聚沉淀作用，而且由于陽極的氧化作用和陰極的還原作用，能去除水中多種污染物。</p><p> 以鐵電極為例：在電解過程中，陽極釋放的 Fe2+ 和溶液中的 Fe3+ 會(huì)與以磷酸根形式存在的磷發(fā)生反應(yīng)生成難溶性鐵鹽。另外，部分 Fe2+ 和 Fe3+ 在一定的 pH范圍內(nèi)與溶液中的 OH- 反應(yīng)生成難溶性的鐵的羥基化合物，這些含鐵的羥基絡(luò)合物能發(fā)生膠體絮凝，從而達(dá)到處理水質(zhì)的作用。</p><p>主要反應(yīng)如下：</p><p>陽極：</p><p>Fe-e- = Fe2+ ； (1)</p><p>陰極：</p><p>2H+ +2e- = H2 ； (2)</p><p>在溶液中：</p><p>4Fe2+ +H2O +O2 = 4Fe3+ +4OH - ， (3)</p><p>Fe3+ +PO43- = FePO4↓， (4)</p><p>3Fe2+ +2PO43- = Fe3(PO4)2 ↓， (5)</p><p>Fe2+ +2OH- = Fe(OH)2 ↓， (6)</p><p>4Fe(OH)2 +O2 +2H2O = 4Fe(OH)3 ↓。 (7)</p> </div> </div> <div id="tmyrlzez" class="cl"></div> <div id="tmyrlzez" class="ye"> 上一條：<a 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